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A recent computational study—using both DFT and ab initio methods—shows that there is a mixing between Co 4+ =O and Co 3+ –O • in a cobalt–oxo complex, with the former a breach of the oxo wall, and the extent of which can be tuned by varying the ligand architecture [67].) Metal–oxo complexes with the metal in a high oxidation state (as in Fe 4+ O and Mn 5+ O) cannot be stabilised by multiple bonding to an oxo ligand [63]
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L-Glu also triggered the downregulation of antiapoptotic B-cell lymphoma-2 (Bcl-2) expression [51,58,59,62], upregulation of the Bax/Bcl-2 ratio [64], and release of other proapoptotic proteins, such as cytochrome c [58,61]
